Beş Dekadlık Anlaşmazlık: Bir Triptik

Özet (abstract)

In his 2004 Priestley Medal address, E. J. Corey stated that in May 1964, he had suggested to R. B. Woodward a frontier molecular orbital explanation for the stereochemistry of electrocyclic reactions-a MO tool that subsequently became foundational to the Woodward-Hoffmann rules. This article examines the resultant controversy from Roald Hoffmann's personal experiences and perspective and completes a triptych of accounts of the prolonged Corey-Woodward dispute. Drawing on contemporaneous correspondence (letters and emails), archival records, laboratory notebooks, published statements, and extensive interviews with Hoffmann and Corey and many others including Albert Eschenmoser over two decades, it reconstructs Hoffmann's scientific and personal interactions with Corey and Woodward from the early 1960s onward. Particular attention is given to Corey's communications following the announcement of Hoffmann's 1981 Nobel Prize, his expectation that Hoffmann publicly validate his allegation against Woodward, and the continuing and lasting emotional and ethical consequences for Hoffmann. The evidence reveals not a simple dispute over priority, but a conflict shaped by idiosyncratic memories and perspectives, asymmetries of professional authority, delayed claims, conflicting loyalties, and fundamentally different conceptions of truth, credit, and responsibility. Hoffmann regarded Corey's recollection of the May 1964 encounter as subjectively credible while rejecting the demand that he judge or publicly support a claim that Corey had not raised directly with Woodward during Woodward's lifetime. The episode illustrates how disputes over scientific credit and collaborative relationships extend beyond the norms of collegial interactions and documentary evidence of discovery to involve character, memory, friendship, trauma, empathy, and the human relationships through which science is created and its history written.

Yazarların özeti; kaynağından alınmıştır. The Chemical Record, 2026 · DOI ↗