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Chemistry - A European Journal· 2012Q1

Supramolecular Binding Thermodynamics by Dispersion‐Corrected Density Functional Theory

Stefan Grimme

Short summary

Dispersion-corrected density functional theory (DFT-D3) with extended basis sets and the COSMO-RS solvation model accurately predicts supramolecular binding free enthalpies (ΔG(a)) with an average error of only 2 kcal mol(-1).

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Field: Atomic and Molecular Physics, and Optics

Atomic and Molecular Physics, and OpticsPhysics and Astronomy