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The Journal of Physical Chemistry A· 2018Q2

Steric Crowding in Tetrel Bonds

Steve Scheiner

Short summary

Tetrel bond strength increases up to 54 kcal/mol with larger central atoms (Si, Ge, Sn, Pb), electron-withdrawing groups (-CF3), and anionic bases, despite steric crowding from bulky R groups (H, CH3, isopropyl, tert-butyl).

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Field: Archeology (Social Sciences)

ArcheologySocial Sciences