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Journal of the Physical Society of Japan· 2026Q2

Large Single Crystal Growth and Transport Properties of KCd 4 As 3 and RbCd 4 As 3

Keigo Ono, Yosuke Goto, Masayuki Murata, Hiroyasu Matsuura et al.

Short summary

Large, centimeter-sized single crystals of KCd 4 As 3 and RbCd 4 As 3 were successfully grown using a Cd 2 As flux method, exhibiting metal-like electrical resistivity and negative Seebeck coefficients, identifying them as n-type thermoelectric materials.

AI-generated from the title and abstract; the full text is not read.

Key points

  • Large single crystals (up to centimeter-size) of KCd 4 As 3 and RbCd 4 As 3 were grown using a Cd 2 As flux.
  • The electrical resistivity of both materials shows a metal-like temperature dependence.
  • Negative Seebeck coefficients were observed, classifying them as n-type thermoelectric materials.

AI-generated from the title and abstract; the full text is not read.

Abstract

Large-size KCd 4 As 3 and RbCd 4 As 3 single crystals were grown using the flux method. Appropriate flux for growing single crystals was determined to be Cd 2 As, resulting in the increase in their size to be a centimeter for KCd 4 As 3 . The KCd 4 As 3 and RbCd 4 As 3 crystals exhibited metal-like temperature dependences of their electrical resistivities with negative Seebeck coefficients, characterizing them as n-type thermoelectric materials.

The authors' abstract, as published at the source. Journal of the Physical Society of Japan, 2026 · DOI ↗

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Field: Materials Chemistry

Materials ChemistryMaterials Science