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Molecules· 2026Q1

Structural Characterization and Visible-Light Photocatalytic Performance of AgBr-Modified Zr-Containing Titanium Silicalite-1 (TS-1) Composites

Hristina I. Lazarova, Elena Tacheva, Borislav Z. Barbov, Rusi Rusew et al.

Short summary

AgBr-modified Zr-containing titanium silicalite-1 (TS-1) composites achieved 98.6% methyl orange removal under visible light in 50 minutes, a significant enhancement over unmodified materials.

AI-generated from the title and abstract; the full text is not read.

Key points

  • AgBr modification significantly boosts the visible-light photocatalytic activity of Zr-containing TS-1.
  • Composites achieved 98.6% methyl orange removal in 50 minutes under white-light irradiation.
  • The MFI framework structure was preserved after AgBr modification.
  • AgBr component is primarily responsible for the enhanced visible-light absorption.
  • The material maintained high activity over five consecutive reaction cycles.

AI-generated from the title and abstract; the full text is not read.

Abstract

AgBr-modified Zr-containing titanium silicalite-1 (TS-1) composites were prepared and evaluated for methyl orange (MO) removal under white-light irradiation. AgBr modification markedly enhanced the visible-light response of the Zr-containing TS-1 materials, resulting in MO removal efficiencies of up to 98.6% after 50 min of irradiation. Structural and textural characterization confirmed preservation of the MFI framework after modification, while diffuse-reflectance measurements showed that the visible-light absorption of the composites is predominantly governed by the AgBr component. The composites retained substantial activity over five consecutive cycles, and scavenger experiments indicated a possible contribution of hydroxyl radicals to MO removal. These results demonstrate that AgBr modification is an effective strategy for enhancing the visible-light activity of Zr-containing TS-1 materials.

The authors' abstract, as published at the source. Molecules, 2026 · DOI ↗

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry