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Scientific Reports· 2026Q1

Role of bio-polymeric binders on combustion and fire suppression performance of KNO3/KClO4–3,5 DNB pyrotechnic composite

Raj Kumar, Eric Niringiyimana, Naina Gautam, Preeti Rathee et al.

Short summary

Replacing synthetic binders with starch in pyrotechnic composites (PCs) significantly improves fire suppression, with starch-based PCs extinguishing a 4.57 kW n-heptane fire in 5s and exhibiting a higher ignition temperature (210°C).

AI-generated from the title and abstract; the full text is not read.

Key points

  • Starch-based pyrotechnic composites (PCs) extinguished a 4.57 kW n-heptane fire in 5s.
  • Starch-based PCs exhibited the highest ignition temperature at 210°C.
  • Linear burning rates for effective PCs ranged from 9.05 to 10.05 mm/s.
  • Bio-binders (starch, guar gum, tannic acid, sodium carboxymethyl cellulose) were evaluated as alternatives to synthetic binders.

AI-generated from the title and abstract; the full text is not read.

Abstract

Traditional pyrotechnic composites (PCs), often synthesized with epoxy or other synthetic binders, can combust at temperatures up to ​ 2100 °C, creating secondary fire and explosion risks. This study examines how renewable, cost-effective binders: starch, guar gum, tannic acid, and sodium carboxymethyl cellulose affect the combustion behavior, exothermicity, temperature profiles, and fire-suppression performance of PCs in a 4.57 kW n-heptane pool fire. Characterization of the aerosol particulates was performed using XRD, FTIR, and SEM. SEM-EDX and DSC for the PCs. PC-1, with a linear burning rate (LBR) of 10.05 ± 2.158 mm/s, extinguished the fire within 5 s and generated the highest ignition temperature (210 °C), whereas PC-4 and PC-5 with LBRs of 9.3 ± 0.742 mm/s and 9.7 ± 0.693 mm/s, respectively showed a noticeable decrease in ignition temperatures (184 °C and 182 °C, respectively) and suppressed the fire within 7 s and 5 s, respectively. It can be concluded that starch-based PC exhibited optimal fire performance parameters, making it a promising bio-based binder for the KNO 3 -KClO 4 -3, 5 DNB pyrotechnic composition.

The authors' abstract, as published at the source. Scientific Reports, 2026 · DOI ↗

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Field: Mechanics of Materials

Mechanics of MaterialsEngineering