He Eklenmesinin DC Ark Plazma Püskürtme Sırasında ZrSiO 4 Tozunun Uçuş Davranışı ve Kaplama Birikimi Üzerindeki Etkisi

Özet (abstract)

ABSTRACT Controlling the surface pyrolysis of ceramic powders during high‐temperature plasma spraying is a critical challenge for producing phase‐pure and structurally integral coatings. Here we show that adding He to the conventional Ar+H 2 plasma working gas effectively suppresses the in‐flight surface pyrolysis of ZrSiO 4 particles while maintaining adequate melting for deposition. By combining CFD simulations, optical emission spectroscopy (OES), and coating microstructure analysis, we demonstrate that He addition induces a synergistic “mild cooling and velocity enhancement” effect. As the He volume fraction increases from 0 to 30 vol.%, the electron excitation temperature decreases linearly from 14 202 to 12 412 K, while the maximum jet velocity rises from 940 to 1271 m/s. This shortens the residence time of particles in the high‐temperature zone and reduces the surface pyrolysis conversion rate from 42.5% to only 12.3% at the optimal He content of 10 vol.%. Excessive He addition (≥30 vol.%) leads to incomplete melting and formation of monoclinic ZrO 2 , degrading coating integrity. This work establishes a quantitative relationship among gas composition, particle in‐flight behavior, and coating phase composition and microstructure, providing a surface‐engineering strategy for plasma processing of high‐temperature ceramic powders.

Yazarların özeti; kaynağından alınmıştır. Journal of the American Ceramic Society, 2026 · DOI ↗