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Inorganic Chemistry· 2026Q1

Unlocking Coordination Chemistry and Photocatalytic Activity of Mn(IV) Complexes with 1,4,6,10-Tetraazaadamantane-Based Tris-Hydroxylamine Ligand TAAD

Kirill I. Sinyushin, Ivan S. Golovanov, Pavel Yu. Ushakov, Vladislav K. Lesnikov et al.

Short summary

A novel tetraazaadamantane-based tris-hydroxylamine ligand (TAAD) stabilizes uncommon [Mn2(μ-OR)3]-dimeric motifs and mononuclear Mn(IV) complexes, which exhibit photocatalytic activity in oxidative azidation/ring-opening reactions.

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry