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ACS Nano· 2026Q1

Chiral Morphology in MoS2 Nanostructures for Spin-Polarized Bifunctional Oxygen Electrocatalysis

Lorenzo Branzi, Fiham Fahim, Niccolò Giaconi, Lapo Querci et al.

Short summary

Chiral metallic 1T-MoS2 nanosheets exhibit enhanced oxygen reduction (ORR) and evolution (OER) catalysis, with performance gains directly linked to spin-polarized charge transport via the chirality-induced spin-selectivity (CISS) effect.

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Key points

  • Chiral morphology of metallic 1T-MoS2 nanosheets can be tuned to modulate spin-dependent properties.
  • The chirality-induced spin-selectivity (CISS) effect is directly correlated with chiral architecture, spin polarization, and electrocatalytic activity.
  • Chiral 1T-MoS2 catalysts show enhanced kinetics and reduced overpotentials for both ORR and OER.
  • Performance gains in oxygen redox reactions are directly linked to spin-polarized charge transport.

AI-generated from the title and abstract; the full text is not read.

Abstract

Abstract Controlling chirality in inorganic nanostructures offers a powerful route to tailoring their electronic and catalytic functions. Here, we demonstrate that the chiral morphology of metallic 1T-MoS2 nanosheets can be precisely tuned to modulate spin-dependent properties via the chirality-induced spin-selectivity (CISS) effect. By systematically varying the handedness and morphology of the nanosheets, we reveal a direct correlation among chiral architecture, spin polarization, and electrocatalytic activity for oxygen redox reactions. Chiral 1T-MoS2 catalysts exhibit remarkably enhanced kinetics and reduced reaction overpotentials for both the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with performance gains directly linked to spin-polarized charge transport. These findings illustrate the advantages of tuning the chiral morphology in transition-metal dichalcogenide nanostructures to tailor spin-dependent properties for advanced catalysis and energy conversion applications.

The authors' abstract, as published at the source. ACS Nano, 2026 · DOI ↗

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Field: Renewable Energy, Sustainability and the Environment

Renewable Energy, Sustainability and the EnvironmentEnergy