Inorganic Chemistry· 2026Q1
Tailoring Reactivity of Molecular Gallium Hydroxides via Chalcogen Bridging
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- 2026year
Short summary
Bridging sulfur (S) or selenium (Se) atoms in digallium dihydroxide complexes [{MeLGa(OH)}2(μ-E)] tune their reactivity, with selenium complexes selectively yielding spirocyclic products with Group 4 metal amides, unlike sulfur complexes which give both monocyclic and spirocyclic products.
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