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Synlett· 2015Q3

Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry

David A. Nicewicz, Hudson Roth, Nathan A. Romero

Short summary

Researchers have experimentally measured and computationally predicted the electrochemical half-peak potentials for over 180 organic molecules, providing crucial data for understanding single-electron transfer processes.

AI-generated from the title and abstract; the full text is not read.

Key points

  • Experimental half-peak potentials measured for over 180 organic substrates via cyclic voltammetry.
  • Data is useful for assessing the thermodynamics of electron transfer processes.
  • A simple computational method for determining redox potentials is also disclosed.

AI-generated from the title and abstract; the full text is not read.

Abstract

Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.

The authors' abstract, as published at the source. Synlett, 2015 · DOI ↗

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Field: Electrochemistry

ElectrochemistryChemistry