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Chemical Science· 2019Q1· Review

A synthetic chemist's guide to electroanalytical tools for studying reaction mechanisms

Christopher Sandford, Martin A. Edwards, Kevin J. Klunder, David P. Hickey et al.

Short summary

Spectroelectrochemistry and scanning electrochemical microscopy offer synthetic chemists powerful tools to probe reaction mechanisms by monitoring redox-active intermediates.

AI-generated from the title and abstract; the full text is not read.

Key points

  • Spectroelectrochemistry and scanning electrochemical microscopy are presented as key electroanalytical tools.
  • These techniques allow for the study of both electrochemically-initiated processes and chemically formed redox intermediates.
  • The article serves as an introduction for synthetic chemists to these methods.
  • The primary application discussed is probing reaction mechanisms.

AI-generated from the title and abstract; the full text is not read.

Abstract

spectroelectrochemistry and scanning electrochemical microscopy. This perspective provides an overview of these tools, with examples of both electrochemically-initiated processes and monitoring redox-active intermediates formed chemically in solution. The article is designed to introduce synthetic organic and organometallic chemists to electroanalytical techniques and their use in probing key mechanistic questions.

The authors' abstract, as published at the source. Chemical Science, 2019 · DOI ↗

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Field: Electrochemistry

ElectrochemistryChemistry