Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry· 2013
Empirical Formulae to Molecular Structures of Metal Complexes by Molar Conductance
- 327citations
- 2013year
Short summary
Molar conductance data can predict metal complex geometries and metal-ligand stoichiometry, and reveal structural variance across solvents.
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Key points
- Molar conductance studies provide insights into the electrolytic behavior and composition of metal complex solutions.
- Data can be used to ascertain electrolytic vs. non-electrolytic nature and predict metal complex geometries.
- Molar conductance is applied to estimate the size of structurally relevant complexes and determine metal-ligand stoichiometry.
- Measurements reveal structural variance of metal complexes in different solvents.
AI-generated from the title and abstract; the full text is not read.
Abstract
Molar conductance studies of electrolytic solutions have always been exciting for chemists. The studies of electrolytic behavior of metal complex solutions provide brief insights into their nature and composition. These studies provide a clue of the number of ions present in a particular solution responsible for the conduction of electric current and, thereby, quite significant structural information can be obtained. Molar conductance data are exploited to ascertain electrolytic and non-electrolytic nature of metal complexes. Attempts have been made to summarize molar conductance ranges of metal complexes in various solvents, which might prove useful to researchers and academia. Besides, molar conductance data have been applied to predict geometries of metal complexes. Moreover, efforts have been made to discuss the applications of conductance data for the estimation of the size of structurally relevant complexes. In addition, molar conductance has been applied to determine metal-ligand stoichiometry. Finally, the structural variance of metal complexes in different solvents is discussed in terms of molar conductance measurements.
The authors' abstract, as published at the source. Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2013 · DOI ↗
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Field: Electrochemistry
ElectrochemistryChemistry