Angewandte Chemie International Edition· 2012Q1
Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
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- 2012year
Short summary
PCN-222, a mesoporous metal-organic framework (MOF) assembled from Zr6 clusters and metalloporphyrins, exhibits ultrahigh stability and ultra-large 1D channels, functioning as a biomimetic catalyst.
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Key points
- PCN-222 is a mesoporous MOF assembled from Zr6 clusters and metalloporphyrins.
- It possesses ultrahigh stability and ultra-large 1D channels.
- PCN-222(Fe) exhibits peroxidase-like biomimetic catalytic activity.
- The MOF effectively catalyzes oxidation of various substrates in aqueous solution.
AI-generated from the title and abstract; the full text is not read.
Abstract
Biomimetic MOF: Extremely stable MOFs with different open metal sites and ultra-large 1D channels, PCN-222 (Fe, Mn, Co, Ni, Cu, and Zn), have been assembled with eight-connected Zr6 clusters and redox-active metalloporphyrin motifs. PCN-222(Fe) shows peroxidase-like activity in aqueous solution, exhibiting highly effective biomimetic oxidation on a number of substrates. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
The authors' abstract, as published at the source. Angewandte Chemie International Edition, 2012 · DOI ↗
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Field: Inorganic Chemistry
Inorganic ChemistryChemistry