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Advanced Materials· 2017Q1· Review

Metal–Organic Frameworks as Platforms for Catalytic Applications

Long Jiao, Yang Wang, Hai‐Long Jiang, Qiang Xü

Short summary

Metal-organic frameworks (MOFs) are versatile crystalline porous materials suitable for catalysis, with recent developments focusing on heterogeneous, photo-, and electrocatalysis.

AI-generated from the title and abstract; the full text is not read.

Key points

  • MOFs are crystalline porous materials built from organic linkers and metal ions/clusters.
  • Their structural diversity, tailorability, and high surface area make them versatile for catalysis.
  • Recent MOF catalysis research covers heterogeneous, photocatalysis, and electrocatalysis.
  • The review emphasizes the active sites involved in MOF-based catalysts.

AI-generated from the title and abstract; the full text is not read.

Abstract

Metal-organic frameworks (MOFs), also called porous coordination polymers, represent a class of crystalline porous materials built from organic linkers and metal ions/clusters. The unique features of MOFs, including structural diversity and tailorability as well as high surface area, etc., enable them to be a highly versatile platform for potential applications in many fields. Herein, an overview of recent developments achieved in MOF catalysis, including heterogeneous catalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided. The active sites involved in the catalysts are particularly emphasized. The challenges, future trends, and prospects associated with MOFs and their related materials for catalysis are also discussed.

The authors' abstract, as published at the source. Advanced Materials, 2017 · DOI ↗

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry