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Chemical Society Reviews· 2014Q1· Review

MOFs as proton conductors – challenges and opportunities

Padmini Ramaswamy, Norman E. Wong, George K. H. Shimizu

Short summary

Metal-Organic Frameworks (MOFs) show promise as proton-conducting electrolytes for fuel cells due to their tunable, crystalline structures and functionalizable pores.

AI-generated from the title and abstract; the full text is not read.

Key points

  • MOFs are being investigated as proton-conducting electrolytes for fuel cells.
  • Key advantages of MOFs include crystallinity, functionalizable pores, and structural tunability.
  • These properties allow for the design of MOFs optimized for specific operating conditions (temperature, humidity).
  • The review focuses on the design, synthesis, and properties of proton-conducting MOFs.

AI-generated from the title and abstract; the full text is not read.

Abstract

Proton conducting materials have garnered immense attention for their role as electrolytes in fuel cells. Metal Organic Frameworks (MOFs) and coordination polymers have recently been investigated as possible candidates for proton-conducting applications. Their crystallinity, chemically functionalizable pores and options for systematic structural variation are some of the factors that allow for the targeted design of better proton conductors operating over a wide variety of temperatures and/or humidity conditions. This review will examine selected examples from this nascent field, and will focus on the design and synthesis of proton conducting MOFs, their properties and conditions under which they operate.

The authors' abstract, as published at the source. Chemical Society Reviews, 2014 · DOI ↗

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry