JACS Au· 2026Q1
Reductive and Oxidative Transformations of Nitrite at Nickel(II): Insights into the Generation, Electronic Structure, and Reactivity of {NiNO} <sup>10</sup>
- 1citations
- Q1SCImago
- 2026year
Short summary
This study demonstrates novel nickel(II) complex pathways for converting nitrite to nitrate via stepwise oxygen atom transfer and for generating a {NiNO}10 species through nitrite-thiol/H2S crosstalk. It also uniquely shows nitrous acid (HNO2) as an intermediate in nitrite reduction.
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CatalysisChemical Engineering