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ACS Applied Polymer Materials· 2026Q1

Network Formation and Structure–Property Relationships in Photoinduced Inverse Vulcanization

Chunxue Li, Yiqian Chen, Jie Lin, Feiping Zhao et al.

Short summary

Photoinduced inverse vulcanization at 435 nm converts sulfur and 1,3-diisopropenylbenzene (DIB) into sulfur-rich polymers, with network formation peaking within 6 hours, increasing Tg from -7.1 to 52.3°C, and achieving 82% insoluble fraction.

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Polymers and PlasticsMaterials Science