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Advanced Materials· 2013Q1· Review

25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials

Michael Naguib, Vadym N. Mochalin, Michel W. Barsoum, Yury Gogotsi

Short summary

MXenes, a new class of 2D materials derived from MAX phases, combine metallic conductivity with hydrophilic surfaces, behaving like 'conductive clays'.

AI-generated from the title and abstract; the full text is not read.

Key points

  • MXenes are a new family of 2D materials produced by etching MAX phases.
  • They possess metallic conductivity and hydrophilic, terminated surfaces.
  • They are described as 'conductive clays' due to their properties.
  • Promising initial applications are seen in electrochemical energy storage.

AI-generated from the title and abstract; the full text is not read.

Abstract

Recently a new, large family of two-dimensional (2D) early transition metal carbides and carbonitrides, called MXenes, was discovered. MXenes are produced by selective etching of the A element from the MAX phases, which are metallically conductive, layered solids connected by strong metallic, ionic, and covalent bonds, such as Ti2 AlC, Ti3 AlC2 , and Ta4 AlC3 . MXenes -combine the metallic conductivity of transition metal carbides with the hydrophilic nature of their hydroxyl or oxygen terminated surfaces. In essence, they behave as "conductive clays". This article reviews progress-both -experimental and theoretical-on their synthesis, structure, properties, intercalation, delamination, and potential applications. MXenes are expected to be good candidates for a host of applications. They have already shown promising performance in electrochemical energy storage systems. A detailed outlook for future research on MXenes is also presented.

The authors' abstract, as published at the source. Advanced Materials, 2013 · DOI ↗

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Field: Materials Chemistry

Materials ChemistryMaterials Science