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Organic Letters· 2026Q1

Dynamic Clipping Synthesis of Rotaxanes via Siliconate-Forming Reaction from Bis-Catechol, Organotrimethoxysilanes, and Secondary Amines

Takumi Takizawa, Masaya Naito, Shinobu Miyagawa, Yuji Tokunaga

Short summary

A novel dynamic clipping method synthesizes [2]rotaxanes using bis-catechol, organotrimethoxysilanes, and secondary amines, forming stable interlocked structures via catechol siliconate ions.

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Field: Organic Chemistry

Organic ChemistryChemistry