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Angewandte Chemie International Edition· 2012Q1

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition‐Metal Complexes

Eric M. Simmons, John F. Hartwig

Short summary

A primary deuterium kinetic isotope effect (KIE) in CH bond functionalization does not always indicate C-H bond cleavage in the rate-determining step.

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry