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Science· 2012Q1

Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites

Eric D. Bloch, Wendy L. Queen, Rajamani Krishna, Joseph M. Zadrozny et al.

Short summary

The metal-organic framework Fe(2)(dobdc) selectively separates ethylene/ethane and propylene/propane mixtures at 318 K, with acetylene, ethylene, and propylene coordinating to iron(II) sites.

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry