Angewandte Chemie International Edition· 2012Q1
An Amine‐Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible‐Light‐Induced Activity for CO<sub>2</sub> Reduction
- 1,711citations
- Q1SCImago
- 2012year
Short summary
A titanium metal-organic framework, NH2-MIL-125(Ti), demonstrates visible-light photocatalytic reduction of CO2 to formate for the first time.
AI-generated from the title and abstract; the full text is not read.
Key points
- NH2-MIL-125(Ti), a titanium metal-organic framework, is synthesized via ligand substitution in MIL-125(Ti).
- The material exhibits photocatalytic activity under visible light irradiation.
- It successfully reduces carbon dioxide to the formate anion.
- This is the first demonstration of visible-light CO2 reduction using a Ti-MOF.
AI-generated from the title and abstract; the full text is not read.
Abstract
Let your light shine: The photocatalytic reduction of carbon dioxide to the formate anion under visible light irradiation is for the first time realized over a photoactive Ti-containing metal–organic framework, NH2-MIL-125(Ti), which is fabricated by a facile substitution of ligands in the UV-responsive MIL-125(Ti) material (see scheme; TEOA=triethanolamine). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
The authors' abstract, as published at the source. Angewandte Chemie International Edition, 2012 · DOI ↗
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Field: Inorganic Chemistry
Inorganic ChemistryChemistry