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Chemistry of Materials· 2016Q1

Defect Engineering: Tuning the Porosity and Composition of the Metal–Organic Framework UiO-66 via Modulated Synthesis

Greig C. Shearer, Sachin Chavan, Silvia Bordiga, Stian Svelle et al.

Short summary

Missing cluster defects in UiO-66 MOFs can be precisely controlled by adjusting the concentration and acidity of monocarboxylic acid modulators during synthesis, thereby tuning the material's porosity and composition.

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Field: Inorganic Chemistry

Inorganic ChemistryChemistry