Journal of the American Chemical Society· 2013Q1
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption
- 1,444citations
- Q1SCImago
- 2013year
Short summary
UiO-66 metal-organic framework (MOF) crystals contain significant, tunable missing-linker defects (up to ~10%) that increase pore volume by ~150% and BET surface area by ~60% compared to defect-free structures, leading to dramatically enhanced gas adsorption, particularly for CO2.
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Inorganic ChemistryChemistry