Angewandte Chemie International Edition· 2013Q1
Highly Selective Detection of Nitro Explosives by a Luminescent Metal–Organic Framework
- 1,344citations
- Q1SCImago
- 2013year
Short summary
A luminescent metal–organic framework, [Cd(NDC)0.5(PCA)]⋅Gx, selectively detects 2,4,6-trinitrophenol (TNP) in mixed nitro explosive solutions via electron/energy transfer and electrostatic interactions.
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Key points
- A new fluorescent metal–organic framework, [Cd(NDC)0.5(PCA)]⋅Gx, has been synthesized.
- The MOF exhibits high selectivity for detecting 2,4,6-trinitrophenol (TNP).
- Detection is effective in mixed solutions containing other nitro explosives.
- Mechanisms include electron transfer, energy transfer, and electrostatic interactions.
AI-generated from the title and abstract; the full text is not read.
Abstract
TNP can't hide from MOF: A three-dimensional fluorescent metal–organic framework (MOF), [Cd(NDC)0.5(PCA)]⋅Gx, can be used for the detection of 2,4,6-trinitrophenol (TNP). The MOF exhibits high selectivity towards TNP, even in the presence of other nitro explosives in aqueous and organic solutions, owing to electron- and energy-transfer mechanisms and electrostatic interactions. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
The authors' abstract, as published at the source. Angewandte Chemie International Edition, 2013 · DOI ↗
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Field: Inorganic Chemistry
Inorganic ChemistryChemistry