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Journal of Chemical Theory and Computation· 2013Q1

Intrinsic Atomic Orbitals: An Unbiased Bridge between Quantum Theory and Chemical Concepts

Gerald Knizia

Short summary

A simple algebraic construction defines polarized atomic orbitals that exactly represent quantum chemistry wave functions, directly connecting theory to chemical concepts like bonding and electronegativity.

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Field: Spectroscopy

SpectroscopyChemistry