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Angewandte Chemie International Edition· 2014Q1· Review

Mixed Transition‐Metal Oxides: Design, Synthesis, and Energy‐Related Applications

Changzhou Yuan, Hao Bin Wu, Yi Xie, Xiong Wen Lou

Short summary

Mixed transition-metal oxides (MTMOs) with spinel structures (Ax B3-x O4) show promise for low-cost, eco-friendly energy storage and conversion.

AI-generated from the title and abstract; the full text is not read.

Key points

  • MTMOs (Ax B3-x O4) with spinel structures are a promising class of materials for energy applications.
  • Research focuses on rational design and efficient synthesis of MTMOs with controlled properties.
  • Applications include electrode materials for lithium-ion batteries and electrochemical capacitors.
  • MTMOs are also used as electrocatalysts for the oxygen reduction reaction in metal-air batteries and fuel cells.

AI-generated from the title and abstract; the full text is not read.

Abstract

A promising family of mixed transition-metal oxides (MTMOs) (designated as Ax B3-x O4 ; A, B=Co, Ni, Zn, Mn, Fe, etc.) with stoichiometric or even non-stoichiometric compositions, typically in a spinel structure, has recently attracted increasing research interest worldwide. Benefiting from their remarkable electrochemical properties, these MTMOs will play significant roles for low-cost and environmentally friendly energy storage/conversion technologies. In this Review, we summarize recent research advances in the rational design and efficient synthesis of MTMOs with controlled shapes, sizes, compositions, and micro-/nanostructures, along with their applications as electrode materials for lithium-ion batteries and electrochemical capacitors, and efficient electrocatalysts for the oxygen reduction reaction in metal-air batteries and fuel cells. Some future trends and prospects to further develop advanced MTMOs for next-generation electrochemical energy storage/conversion systems are also presented.

The authors' abstract, as published at the source. Angewandte Chemie International Edition, 2014 · DOI ↗

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Field: Electronic, Optical and Magnetic Materials

Electronic, Optical and Magnetic MaterialsMaterials Science