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Chemical Society Reviews· 2012Q1· Review

Self-assembly of block copolymers

Yiyong Mai, Adi Eisenberg

Short summary

Block copolymers (BCPs) self-assemble into diverse ordered structures like spheres, cylinders, and lamellae, offering potential applications across various fields.

AI-generated from the title and abstract; the full text is not read.

Key points

  • BCPs self-assemble into ordered structures like spheres, cylinders, lamellae, and vesicles.
  • These aggregates have potential applications in many fields.
  • The review covers principles of BCP self-assembly in bulk and solution.
  • It discusses experiments, theories, morphologies, and influencing factors.

AI-generated from the title and abstract; the full text is not read.

Abstract

Block copolymer (BCP) self-assembly has attracted considerable attention for many decades because it can yield ordered structures in a wide range of morphologies, including spheres, cylinders, bicontinuous structures, lamellae, vesicles, and many other complex or hierarchical assemblies. These aggregates provide potential or practical applications in many fields. The present tutorial review introduces the primary principles of BCP self-assembly in bulk and in solution, by describing experiments, theories, accessible morphologies and morphological transitions, factors affecting the morphology, thermodynamics and kinetics, among others. As one specific example at a more advanced level, BCP vesicles (polymersomes) and their potential applications are discussed in some detail.

The authors' abstract, as published at the source. Chemical Society Reviews, 2012 · DOI ↗

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Field: Organic Chemistry

Organic ChemistryChemistry