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ChemPhysChem· 2015Q2· Review

The Bright Future of Unconventional σ/π‐Hole Interactions

Antonio Bauzá, Tiddo J. Mooibroek, Antonio Frontera

Short summary

σ- and π-holes, regions of positive electrostatic potential on unpopulated orbitals, can interact with electron-dense regions, forming novel non-covalent bonds like chalcogen, pnictogen, tetrel, anion-π, and lone-pair-π interactions.

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Field: Physical and Theoretical Chemistry

Physical and Theoretical ChemistryChemistry