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Chemical Reviews· 2016Q1· Review

σ-Hole Bond vs π-Hole Bond: A Comparison Based on Halogen Bond

Hui Wang, Weizhou Wang, Wei Jun Jin

Short summary

σ-hole bonds and π-hole bonds are directional noncovalent interactions arising from positive electrostatic potential regions on molecules, distinct from halogen bonds.

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Field: Physical and Theoretical Chemistry

Physical and Theoretical ChemistryChemistry