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Physical Chemistry Chemical Physics· 2013Q2

Halogen bonding and other σ-hole interactions: a perspective

Peter Politzer, Jane S. Murray, Timothy Clark

Short summary

σ-hole bonds are noncovalent interactions involving a positively charged region (σ-hole) on an atom and a negative site, with halogen bonding being a specific type. These interactions are primarily driven by electrostatics and polarization.

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Field: Physical and Theoretical Chemistry

Physical and Theoretical ChemistryChemistry