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The Journal of Organic Chemistry· 2025Q2

Semiheterogeneous Intrinsic FeTiO3-Photoredox/Ph3N Dual-Catalyzed Fluoroalkylation of N-Heteroarenes with Alkenes and RfSO2Cl

Qiong-Hui Peng, Ying-Li Cai, Hui Dai, Chunlin Zhuang et al.

Short summary

A new semiheterogeneous method uses intrinsic FeTiO3 as a photocatalyst and Ph3N as a redox mediator to fluoroalkylate N-heteroarenes with alkenes and RfSO2Cl, achieving high yields and functional-group tolerance without sacrificial reagents.

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