Angewandte Chemie International Edition· 2012Q1· Review
Catalytic Asymmetric Dearomatization Reactions
- 1,299citations
- Q1SCImago
- 2012year
Short summary
This review summarizes the development of catalytic asymmetric dearomatization (CADA) reactions, presenting a conceptual framework for these transformations.
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Key points
- Summarizes the development of catalytic asymmetric dearomatization (CADA) reactions.
- Discusses diverse CADA reaction types: oxidative, Diels-Alder, alkylative, transition-metal-catalyzed, nucleophilic, and cascade sequences.
- Includes CADA reactions with chiral auxiliaries and dearomatized substrates.
- Provides a conceptual framework for understanding CADA reactions.
AI-generated from the title and abstract; the full text is not read.
Abstract
This Review summarizes the development of catalytic asymmetric dearomatization (CADA) reactions. The CADA reactions discussed herein include oxidative dearomatization reactions, dearomatization by Diels-Alder and related reactions, the alkylative dearomatization of electron-rich arenes, transition-metal-catalyzed dearomatization reactions, cascade sequences involving asymmetric dearomatization as the key step, and nucleophilic dearomatization reactions of pyridinium derivatives. Asymmetric dearomatization reactions with chiral auxiliaries and catalytic asymmetric reactions of dearomatized substrates are also briefly introduced. This Review intends to provide a concept for catalytic asymmetric dearomatization.
The authors' abstract, as published at the source. Angewandte Chemie International Edition, 2012 · DOI ↗
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Field: Organic Chemistry
Organic ChemistryChemistry