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Angewandte Chemie International Edition· 2019Q1· Review

Mechanochemistry for Synthesis

Tomislav Friščić, Cristina Mottillo, Hatem M. Titi

Short summary

Mechanochemistry, using solvent-free milling or grinding, enables the synthesis of molecules and materials previously inaccessible in solution.

AI-generated from the title and abstract; the full text is not read.

Key points

  • Mechanochemistry eliminates the need for bulk solvents in chemical reactions.
  • It provides a unique reaction environment not achievable in solution.
  • Ball milling is a key technique for mechanochemical synthesis.
  • Mechanochemistry facilitates the formation of both covalent and coordination bonds.

AI-generated from the title and abstract; the full text is not read.

Abstract

Mechanochemical solvent-free reactions by milling, grinding or other types of mechanical action have emerged as a viable alternative to solution chemistry. Mechanochemistry offers not only a possibility to eliminate the need for bulk solvent use, and reduce the generation of waste, but it also unlocks the door to a different reaction environment in which synthetic strategies, reactions and molecules previously not accessible in solution, can be achieved. This Minireview examines the potential of mechanochemistry in chemical and materials synthesis, by providing a cross-section of the recent developments in using ball milling for the formation of molecules and materials based on covalent and coordination bonds.

The authors' abstract, as published at the source. Angewandte Chemie International Edition, 2019 · DOI ↗

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Field: Physical and Theoretical Chemistry

Physical and Theoretical ChemistryChemistry