The Journal of Organic Chemistry· 2026Q2
Stereoselective Gateway to Decorated Chloro-1,3-butadienes from Allenols via Deoxygenative 1,2-Bond Migration
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- Q2SCImago
- 2026year
Short summary
A new strategy synthesizes E-2-chloro-1,3-butadienes from allenols via deoxygenative 1,2-bond migration, offering moderate-to-good yields and scalability.
AI-generated from the title and abstract; the full text is not read.
Key points
- Developed a strategy for synthesizing E-2-chloro-1,3-butadienes from allenols.
- The reaction proceeds via a deoxygenative 1,2-bond migration mechanism.
- Achieves moderate-to-good yields with an extensive substrate scope.
- The method is operationally simple, scalable, and offers versatility for further diversification.
AI-generated from the title and abstract; the full text is not read.
Abstract
Abstract We disclose an efficient strategy for the selective synthesis of E-2-chloro-1,3-butadienes from allenols. This modular approach offers an extensive substrate scope with moderate-to-good yields and operational simplicity. Additionally, they offer a versatile platform for synthetic diversification and are highly scalable.
The authors' abstract, as published at the source. The Journal of Organic Chemistry, 2026 · DOI ↗
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Field: Organic Chemistry
Organic ChemistryChemistry